水性丙烯酸环氧树脂乳液的制备与研究.rar
水性丙烯酸环氧树脂乳液的制备与研究,合格作品 字数4266个字摘 要水性涂料具有无毒、无味、环境污染小等优点，符合当今涂料的发展方向。环氧树脂附着力和耐化学药品腐蚀能力强，广泛应用于防腐涂料工业领域。但环氧树脂难溶于水，只溶于有机溶剂，传统的环氧涂料只为溶剂型。以环氧树脂的水性化来开发水性环氧涂料借以取代溶剂型涂料，适应了涂料界节资节能，保护环境的要求。...
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内容介绍
原文档由会员 白痴学东西 发布
合格作品 字数4266个字
摘 要
水性涂料具有无毒、无味、环境污染小等优点，符合当今涂料的发展方向。环氧树脂附着力和耐化学药品腐蚀能力强，广泛应用于防腐涂料工业领域。但环氧树脂难溶于水，只溶于有机溶剂，传统的环氧涂料只为溶剂型。以环氧树脂的水性化来开发水性环氧涂料借以取代溶剂型涂料，适应了涂料界节资节能，保护环境的要求。丙烯酸树脂以其优异的保光保色性，也常用作涂料的基料。因此，可以用丙烯酸酯单体对环氧树脂接枝改性引入羧基等亲水基团，制得水性-丙烯酸环氧树脂，然后中和成盐制得水分散液，兼具了环氧树脂和丙烯酸树脂的优点。
本文研究了水性-丙烯酸环氧树脂接枝共聚物的合成工艺条件，在引发剂过氧化苯甲酰的作用下，将丙烯酸丁酯等单体自由基接枝聚合到环氧树脂上，形成富含羧基等亲水基团的水性-丙烯酸环氧树脂，用成盐剂中和成盐，加水稀释形成水分散液。以单因素实验讨论了混合单体含量、环氧树脂添加量和引发剂占混合单体的比例对合成树脂的影响，测定了所得乳液的固含量、转化率和吸水率，测试了乳液涂膜性能，结果表明乳液性能好，符合要求。
关键词 乳液 单体 接枝反应 水性涂料
Abstract
Water-based paint with non-toxic, tasteless, environmental pollution, etc., with the current paint development. Epoxy adhesion and corrosion resistance to strong chemicals, widely used in anti-corrosion coatings industry. However, epoxy resin is insoluble in water, only soluble in organic solvents, the traditional solvent-based epoxy coatings. With water-based epoxy resin to develop water-based epoxy coatings to replace solvent-based paints, the paint industry to adapt to the section owned energy, environmental protection requirements. Acrylic resin for its excellent gloss and color retention, but also used as coating binders. Therefore, you can use epoxy acrylate monomers grafted on the introduction of carboxyl and other hydrophilic groups, a system of water - acrylic resin, and salt and then the obtained water dispersion system, both the ring epoxy resin and acrylic resin advantages.
This paper studies the water - acrylic graft copolymer resin synthesis process conditions, the initiator benzoyl peroxide under the action of the butyl acrylate and other monomers to free radical graft polymerization of epoxy resin, the formation of hydrophilic groups such as carboxyl-rich water-based - acrylic resin,with a salt agent and salt, diluted with water to form aqueous dispersions. To discuss the single factor experiments hybrid monomer content, add the amount of epoxy resin mixed monomer and initiator proportion accounted for the impact of synthetic resin, measured from the solid content of emulsions, the conversion rate and water absorption test of the emulsion coating Performance results show that the emulsion performance, to meet the requirements.
Key words Emulsion Monomer Grafting reaction Water-based paint
目 录
摘 要 I
Abstract II
第一章 绪论 1
1.1 引言 1
1.2 环氧树脂概述 1
1.3 环氧树脂的水性化改性方法 3
1.3.1 乳化法 3
1.3.2 化学改性法 4
1.4 反应的微观分析 7
1.5 本文研究的目的与意义 8
第二章 实验部分 10
2.1 主要实验原料 10
2.2 主要使用的仪器 10
2.3 水性-丙烯酸环氧树脂乳液的制备 11
2.4 单因素实验设计 12
2.5 乳液性能分析方法 13
2.5.1 外观测定 13
2.5.2 pH值的测定 13
2.5.3 钙离子稳定性 13
2.5.4 机械稳定性 13
2.5.5 固含量的测定 13
2.5.6 单体的转化率 14
2.5.7 涂膜耐水性及吸水率的测定 14
第三章 结果与讨论 16
3.1 单因素实验的结果分析 16
3.1.1 混合单体含量的影响的分析 16
3.1.2 环氧树脂添加量的影响的分析 17
3.1.3 引发剂用量的影响的分析 19
3.2 乳液性能测试结果 21
3.2.1 外观测定 21
3.2.2 乳液pH的测定 21
3.2.3 钙离子稳定性测试 21
3.2.4 乳液机械稳定性测试 21
3.2.5 固含量的测定 21
3.2.6 单体转化率的测定 21
3.2.7 涂膜耐水性及吸水率的测定 21
结 论 23
致 谢 24
参考文献 25
Contents
Chinese abstract I
English abstract II
Chapter one Introduction 1
1.1 Introduction 1
1.2 Epoxy resin summarize 1
1.3 The modification of waterborne epoxy resin method 3
1.3.1 Emulsion process 3
1.3.2 Chemical modification 4
1.4 The reaction microscopic analysis 7
1.5 The purpose of this study and meaning 8
Chapter two Experimental section 10
2.1 The main raw material 10
2.2 The main use of the instrument 10
2.3 Water-acrylic epoxy resin emulsion preparation 11
2.4 Single factor experiment design 12
2.5 Emulsion performance analysis method 13
2.5.1 Appearance determination 13
2.5.2 pH value of determination 13
2.5.3 Calcium ion stability 13
2.5.4 Mechanical stability 13
2.5.5 Solid content determination 13
2.5.6 Monomer conversion 14
2.5.7 The film water resistance and bibulous rate is determined 14
Chapter three Results and Discussion 16
3.1 Single factor experiment analysis of results 16
3.1.1 Mix of analysis on the influence of the monomer content 16
3.1.2 The amount of epoxy resin added to the analysis of the influence 17
3.1.3 Dosage of initiator of the ..
摘 要
水性涂料具有无毒、无味、环境污染小等优点，符合当今涂料的发展方向。环氧树脂附着力和耐化学药品腐蚀能力强，广泛应用于防腐涂料工业领域。但环氧树脂难溶于水，只溶于有机溶剂，传统的环氧涂料只为溶剂型。以环氧树脂的水性化来开发水性环氧涂料借以取代溶剂型涂料，适应了涂料界节资节能，保护环境的要求。丙烯酸树脂以其优异的保光保色性，也常用作涂料的基料。因此，可以用丙烯酸酯单体对环氧树脂接枝改性引入羧基等亲水基团，制得水性-丙烯酸环氧树脂，然后中和成盐制得水分散液，兼具了环氧树脂和丙烯酸树脂的优点。
本文研究了水性-丙烯酸环氧树脂接枝共聚物的合成工艺条件，在引发剂过氧化苯甲酰的作用下，将丙烯酸丁酯等单体自由基接枝聚合到环氧树脂上，形成富含羧基等亲水基团的水性-丙烯酸环氧树脂，用成盐剂中和成盐，加水稀释形成水分散液。以单因素实验讨论了混合单体含量、环氧树脂添加量和引发剂占混合单体的比例对合成树脂的影响，测定了所得乳液的固含量、转化率和吸水率，测试了乳液涂膜性能，结果表明乳液性能好，符合要求。
关键词 乳液 单体 接枝反应 水性涂料
Abstract
Water-based paint with non-toxic, tasteless, environmental pollution, etc., with the current paint development. Epoxy adhesion and corrosion resistance to strong chemicals, widely used in anti-corrosion coatings industry. However, epoxy resin is insoluble in water, only soluble in organic solvents, the traditional solvent-based epoxy coatings. With water-based epoxy resin to develop water-based epoxy coatings to replace solvent-based paints, the paint industry to adapt to the section owned energy, environmental protection requirements. Acrylic resin for its excellent gloss and color retention, but also used as coating binders. Therefore, you can use epoxy acrylate monomers grafted on the introduction of carboxyl and other hydrophilic groups, a system of water - acrylic resin, and salt and then the obtained water dispersion system, both the ring epoxy resin and acrylic resin advantages.
This paper studies the water - acrylic graft copolymer resin synthesis process conditions, the initiator benzoyl peroxide under the action of the butyl acrylate and other monomers to free radical graft polymerization of epoxy resin, the formation of hydrophilic groups such as carboxyl-rich water-based - acrylic resin,with a salt agent and salt, diluted with water to form aqueous dispersions. To discuss the single factor experiments hybrid monomer content, add the amount of epoxy resin mixed monomer and initiator proportion accounted for the impact of synthetic resin, measured from the solid content of emulsions, the conversion rate and water absorption test of the emulsion coating Performance results show that the emulsion performance, to meet the requirements.
Key words Emulsion Monomer Grafting reaction Water-based paint
目 录
摘 要 I
Abstract II
第一章 绪论 1
1.1 引言 1
1.2 环氧树脂概述 1
1.3 环氧树脂的水性化改性方法 3
1.3.1 乳化法 3
1.3.2 化学改性法 4
1.4 反应的微观分析 7
1.5 本文研究的目的与意义 8
第二章 实验部分 10
2.1 主要实验原料 10
2.2 主要使用的仪器 10
2.3 水性-丙烯酸环氧树脂乳液的制备 11
2.4 单因素实验设计 12
2.5 乳液性能分析方法 13
2.5.1 外观测定 13
2.5.2 pH值的测定 13
2.5.3 钙离子稳定性 13
2.5.4 机械稳定性 13
2.5.5 固含量的测定 13
2.5.6 单体的转化率 14
2.5.7 涂膜耐水性及吸水率的测定 14
第三章 结果与讨论 16
3.1 单因素实验的结果分析 16
3.1.1 混合单体含量的影响的分析 16
3.1.2 环氧树脂添加量的影响的分析 17
3.1.3 引发剂用量的影响的分析 19
3.2 乳液性能测试结果 21
3.2.1 外观测定 21
3.2.2 乳液pH的测定 21
3.2.3 钙离子稳定性测试 21
3.2.4 乳液机械稳定性测试 21
3.2.5 固含量的测定 21
3.2.6 单体转化率的测定 21
3.2.7 涂膜耐水性及吸水率的测定 21
结 论 23
致 谢 24
参考文献 25
Contents
Chinese abstract I
English abstract II
Chapter one Introduction 1
1.1 Introduction 1
1.2 Epoxy resin summarize 1
1.3 The modification of waterborne epoxy resin method 3
1.3.1 Emulsion process 3
1.3.2 Chemical modification 4
1.4 The reaction microscopic analysis 7
1.5 The purpose of this study and meaning 8
Chapter two Experimental section 10
2.1 The main raw material 10
2.2 The main use of the instrument 10
2.3 Water-acrylic epoxy resin emulsion preparation 11
2.4 Single factor experiment design 12
2.5 Emulsion performance analysis method 13
2.5.1 Appearance determination 13
2.5.2 pH value of determination 13
2.5.3 Calcium ion stability 13
2.5.4 Mechanical stability 13
2.5.5 Solid content determination 13
2.5.6 Monomer conversion 14
2.5.7 The film water resistance and bibulous rate is determined 14
Chapter three Results and Discussion 16
3.1 Single factor experiment analysis of results 16
3.1.1 Mix of analysis on the influence of the monomer content 16
3.1.2 The amount of epoxy resin added to the analysis of the influence 17
3.1.3 Dosage of initiator of the ..
